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Although we don't support existing native windows profile (on our to-do list), the way it works today is that Safe Family has one active profile/rules in effect at a time. you can easily switch from parent-child or child-parent if you launch the safe family app, tap on the upper right hand corner, you can switch to another profile. Switching from parent to kid will not require a password, while switching from kid to parent will require a password.
I hope this helps!