Moved to Application and Change Control (Solidcore) for better attention
I didnt get your Question ?
You reported that "outlook.exe" is being blocked even when whitelisted. So I would expect a threat event to be record and reported in the Windows Event log. Also have a look at the Solidcore diagnostic logs s3diag.log and solidcore.log in C:\ProgramData\McAfee\Solidcore\Logs. If you could share an example of any error recorded then that might help to diagnose your issue.