Please visit the McAfee Home page (Click Products at top left) to see the list of Products suitable for you. If you wish to protect more PCs and other platform devices such as MAC / Smartphone go for McAfee All Access Suite.
Please see the System requirements section for checking with Compatibility of Operating Systems. Below is the page for Total Protection which says Windows 8 (32 and 64bit) - that should support Win 8 Enterprise logically.
There should be no problem using the consumer products with 8/8.1 Enterprise as the main differences between that edition and the others are volume licensing and lack of Media Center, so it's supported.