nope, UAC has no handle on the ENS console per se (the process for the ENS console is "known" to Windows, its signed etc.). That being said, you may have some flexibility on the UAC settings side (possibly through GPO) to excert some kind of monitoring with UAC over this process. I have never dug into the "UAC backend" so far as there has never been a need to leverage UAC, utilising the password lock for all cases proved to be useful/sufficient to prevent access.
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