When Management of Native Encryption (MNE) is deployed, FileVault adds the currently logged in local user by default. Domain users will not be added unless they are correctly configured for FileVault. See KB79648 (https://kc.mcafee.com/corporate/index?page=content&id=KB79648) for the steps needed to properly configure the Active Directory users for use with FileVault.
For more resources, visit the ServicePortal and search for related content. Also, visit the McAfee Endpoint Encryption Community: https://community.mcafee.com/community/business/data/epoenc.
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